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Dalpke, Raphael: Transport Behavior of Tailored Carbon Nanomembranes. 2020
Inhalt
Contents
Introduction to the Thesis
From Molecular Self-Assembly to Carbon Nanomembranes (CNMs)
Fundamentals of Transmembrane Separation Processes
Diffusion
Knudsen Mechanism
Weber's Disc
Permeance and other Characteristics
Instruments and Techniques
Atomic Force Microscopy (AFM)
Confocal Laser Scanning Microscopy (CLSM)
Contact Angle Goniometry (CAG)
Gas Permeation Measurements
Gravimetric Analyses
Helium Ion Microscopy (HIM)
Isothermal Titration Calorimetry (ITC)
Liquid Scintillation Counting
Nuclear Magnetic Resonance Spectroscopy (NMR)
Optical Microscopy
Reflection-Absorption Infrared Spectroscopy (RAIRS)
Scanning Electron Microscopy (SEM)
Transmission Electron Microscopy (TEM)
Ultraviolet-Visible Spectroscopy (UV-Vis)
X-Ray Photoelectron Spectroscopy (XPS)
Functionalization of Carbon Nanomembranes
Current State of Research
Protein Coupling to Carbon Nanomembranes
Complex Formation with L-Lysine-NTA
Reversible Protein Immobilization
Irreversible Protein Immobilization
Enhanced Coupling Density through Amino-Terminated Self-Assembled-Monolayers
Summary of the Chapter
Transport Processes through Carbon Nanomembranes
Current State of Research
Aqueous Apparent Diffusion Coefficients Determined by Radioactive Tracers
Experimental Setup
Mathematical Model
Preliminary Investigation of Outgassing Effects
Diffusion of Radioisotopes through CNMs in Aqueous Solution
Summary of the Chapter
Carbon Nanomembranes from Alkanethiol Monolayers
Current State of Research
Fundamental Feasibility Check
Detailed Study of 1-Octadecanethiol (ODT)
Fabrication of Mixed CNMs
Summary of the Chapter
Conclusion of the Thesis
Bibliography
Declaration of Academic Honesty
Technical Drawings
Preparation and Functionalization of CNMs
Derivation of the Radioisotopes' Model
Scientific Publications and Contributions of the Author