TY  - JOUR
AB  - The synthesis of a novel centropentacyclic hydrocarbon, centropentaindan 1, has been achieved by fourfold bromination of the readily available difuso-triindan 4 followed by AlBr3-catalysed condensation with two molecules of benzene; functionalization of the two remaining tertiary bridgehead positions of 1 gives the strained, labile dibromide 6, which has been converted into the dimethyl derivative 7, the centrohexacyclic endoperoxide 8, and, again by AlBr3-catalysed condensation with benzene, into centrohexaindan 2.
DA  - 1994
DO  - 10.1039/C39940000609
KW  - Benzoannelated centropolyquinanes
LA  - eng
IS  - 5
M2  - 609
PY  - 1994
SN  - 0022-4936
SP  - 609-610
T2  - Journal of the Chemical Society, Chemical Communications
TI  - Centropentaindan: synthesis and some bridgehead transformations of a novel regular centropolyindan
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-17741950
Y2  - 2024-11-21T21:19:43
ER  -