TY  - JOUR
AB  - The reaction of 9H,10H-4b,9a([1,2]benzenomethano)indeno[1,2-a]indene (triptindan, TRIP) with Cr(CO)6 in Bu2O/THF (9:1) affords a monocomplex (A) together with two bis-Cr(CO)3 complexes (B and C) and one tris-Cr(CO)3 complex (D). The relative yields of the four complexes as well as their tendency to lose Cr(CO)3 are related to stabilizing intramolecular factors. All the Cr(CO)3 units of the complexes A, B, and D are coordinated in the isoclined orientation with respect to the polar axis of the ligand, whereas complex C bears one isoclined and one anticlined Cr(CO)3 unit. The results of X-ray measurements support the hypothesis of weak attractive electronic interactions bonds between the oxygen atoms of the carbonyl groups and polarized faces of benzene rings.
DA  - 1993
DO  - 10.1002/cber.19931260915
KW  - Polycyclic compounds
KW  - Chromium arene complexes
KW  - Centropolyindans
KW  - Stereochemistry
LA  - eng
IS  - 9
M2  - 2053
PY  - 1993
SN  - 0009-2940
SP  - 2053-2060
T2  - Chemische Berichte
TI  - Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-17742348
Y2  - 2024-11-22T12:04:10
ER  -