TY  - JOUR
AB  - 1,2,3-Tris(pentamethylcyclopentadienyl)cyclotriphosphane (1) reacts with selenium to form the insertion product 2,3,4-tris(pentamethylcyclopentadienyl)selenatriphosphetane (2), which is trapped as the selenium-coordinated pentacarbonylchromium complex 4. Compound 4 is the first isolated selenatriphosphetane complex. Reaction of 2 with selenium yields 2,3-bis(pentamethylcyclopentadienyl)selenadiphosphirane (3). 3 replaces thf of Cr(CO)5thf to give the chromium complex 5. The reaction of 3 with K[Fe(CO)2Cp*] leads to the substitution product 6 and the bicyclic phosphane 7. The X-ray structures of 3 and 4 are presented. The dynamic behavior of 3-6 is discussed.
DA  - 1994
DO  - 10.1002/cber.19941270606
KW  - Selenatriphosphetanes
KW  - Selenadiphosphiranes
KW  - Molecular dynamics
KW  - Phosphacycles
KW  - Selenium compounds
LA  - ger
IS  - 6
M2  - 997
PY  - 1994
SN  - 0009-2940
SP  - 997-1001
T2  - Chemische Berichte
TI  - Pentamethylcyclopentadienyl-substituiertes Selenadiphosphiran und Selenatriphosphetan: Synthese, Struktur, Dynamik und einige Reaktionen: Herrn Prof. R. Schmutzler zum 60. Geburtstag gewidmet
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-17743689
Y2  - 2024-11-22T04:08:43
ER  -