TY - JOUR AB - New Observations Concerning the Stereoselectivity of Monoiodocarbene Additions: Contrary to our earlier claim, CHI gives endolexo isomer mixtures with cyclooctene. However, only endo-iodo compounds 7,8,10- 12 are obtained from COD and COT. Tricyclic compound 7 rearranges partially to bicyclic 9. X-ray structure determinations of 7 and 9 were performed. DA - 1993 KW - Cyclooctatetraene KW - Cyclooctadiene KW - endo-Selectivity KW - Iodocarbene, addition to alkenes LA - ger IS - 2 M2 - 499 PY - 1993 SP - 499-502 T2 - Chemische Berichte TI - Neue Beobachtungen zur Stereoselektivitat von Monoiodcarben-Additionen UR - https://nbn-resolving.org/urn:nbn:de:0070-bipr-4919 Y2 - 2024-11-25T01:04:42 ER -