TY  - JOUR
AB  - The reaction of Me5C5GeCH(SiMe3)2 with LiC-(SiMe,)3 affords (Me3Si)3CGeCH(SiMe3)2 (2), the first unsymmetrically substituted dialkylgermylene, which is stable at ambient temperature. In the solid state, the germylene 2 is monomeric, whereas Lappert's germylene [(Me3Si)2CH]2Ge (1) shows a dimeric structure with a Ge=Ge double bond. Steric effects of the additional trimethylsilyl group in 2 are responsible for these drastic changes in the structure. The germylene Me3SiCH2GeCH(SiMe2)2 (3) decomposes at about -20° C.
DA  - 1991
DO  - 10.1021/om00052a002
LA  - eng
IS  - 6
M2  - 1647
PY  - 1991
SN  - 0276-7333
SP  - 1647-1648
T2  - Organometallics
TI  - Synthesis and solid-state structure of (Me3Si)3CGeCH(SiMe3)2, a monomeric dialkylgermylene
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-17747831
Y2  - 2024-11-22T05:07:40
ER  -