TY  - JOUR
AB  - The novel cyclopentadiene HMe4C5CH2CMe2py [py = 2-(4-tert-butyl)pyridyl] 2H has been prepared from tetramethylfulvene and lithiated 2-isopropyl-4-tert-butylpyridine. Lithiation of 2H with Bu n Li and subsequent reaction with FeCl2 yields the ferrocene (2) 2Fe, which crystallizes in the triclinic space group P (1) with a = 8.368(1), b = 8.468(1), c = 14.313(1) Å, [alpha] = 80.64(1), [beta] = 86.67(1), [gamma] = 80.12(1)° and V = 985.4(2) Å (3).
DA  - 1994
KW  - crystal structure
KW  - pyridyl-functionalized cyclopentadienes
KW  - pyridyl-functionalized ferrocene
KW  - Hemilabile cyclopentadienyl ligands
LA  - eng
IS  - 5
M2  - 683
PY  - 1994
SN  - 0932-0776
SP  - 683-686
T2  - Zeitschrift für Naturforschung, B: Chemical Sciences
TI  - A pentamethylcyclopentadienyl ligand functionalized with a pendant pyridyl group - crystal-structure of its ferrocene-type iron complex
UR  - https://nbn-resolving.org/urn:nbn:de:0070-bipr-6328
Y2  - 2024-11-22T05:03:20
ER  -