TY  - JOUR
AB  - The dichlorophosphido complexes ([eta]5-C5Me5)(CO)2M-PCl2 (2a: M = Fe; 2c: M = Ru) react with two equivalents of Ph2C = NSiMe, to yield the first [eta]1-2,4-diaza-3-phosphapenta-1,4-dien-3-yl complexes (4a,c). Intermediates ([eta]5-C5Me5)(CO)2M-P(Cl)(N = CPh2) (3a,c) are detected by 31P{1H} NMR spectroscopy, the preparation of pure 3a, however, failed. The products 4a,c have been characterized by elemental analysis as well as spectroscopic data (IR, 1H, 13C, 31P NMR, MS). The molecular structure of 4a has been elucidated by single X-ray analysis.
DA  - 1991
KW  - Diazaphosphapentadienyl complex
KW  - iron
KW  - x-ray
KW  - ruthenium
LA  - ger
IS  - 6
M2  - 714
PY  - 1991
SN  - 0932-0776
SP  - 714-718
T2  - Zeitschrift für Naturforschung, B: Chemical Sciences
TI  - Synthese und Struktur von η1-2,4-Diaza-3-phosphapenta-1,4-dien-3-yl-Komplexen des Eisens und Rutheniums
UR  - https://nbn-resolving.org/urn:nbn:de:0070-bipr-6359
Y2  - 2024-11-22T08:48:37
ER  -