TY  - JOUR
AB  - The synthesis of triptindans 13a - e substituted by methoxy and/or methyl groups in positions 2,4,5,7,13, and 15 has been achieved by acid-catalysed cyclodehydration of the corresponding 2,2-dibenzyl-1-indanones 12a - e using Amberlyst 15 and polyphosphoric acid, respectively. Total demethylation of 13a followed by selective deoxygenation of the resulting hexahydroxy compound 14 affords the 4,5,15-trihydroxytriptindan (17) (4, R=OH) bearing the three substituents in its molecular cavity.
DA  - 1987
DO  - 10.1002/cber.19871200420
LA  - ger
IS  - 4
M2  - 589
PY  - 1987
SN  - 0009-2940
SP  - 589-595
T2  - Chemische Berichte
TI  - Benzoanellierte Centropolyquinane, 3 Synthese mehrfach substituierter Triptindane (9H, 10H-4b, 9a-([1,2]Benzenomethano)indeno[1,2-a]indene) mit drei Substituenten in ihrer Molekülhöhlung
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-17758516
Y2  - 2024-11-24T05:00:19
ER  -