TY  - JOUR
AB  - 2-Benzylindenes are hydrogenated to 2-benzylindanes using tris-(triphenylphosphine)-rhodium(I)-chloride in benzene by a strict cis-1,2 addition of hydrogen to the double bond. Thus, stereo- and region-specific deuterium labelling at the five-membered ring of various 2-benzylindanes has been carried out. The high selectivity of deuterium incorporation is shown independently by 1H NMR and mass (MIKE) spectrometry of selected 2-benzylindanes.
DA  - 1984
DO  - 10.1515/znb-1984-0316
KW  - Stereochemistry
KW  - Indanes
KW  - Indenes
KW  - Deuterium labelling
KW  - Homogeneous catalytic hydrogenation
LA  - eng
IS  - 3
M2  - 369
PY  - 1984
SN  - 0340-5087
SP  - 369-374
T2  - Zeitschrift für Naturforschung B, Journal of Chemical Sciences
TI  - Synthesis of regio- and stereospecifically deuterium labelled 2-benzylindanes
UR  - https://nbn-resolving.org/urn:nbn:de:0070-bipr-13111
Y2  - 2024-11-25T12:00:57
ER  -