TY  - JOUR
AB  - The preparation of the title compound 1 via an 8-step synthesis starting with 3-nitrobenz-aldehyde and with a yield of 5.5% is described. 1 is a heteracarbophane with an azo bridge connecting the two benzene rings. In CHCl3 solution 1 is a mixture of the syn- and anti-form and the special steric requirements of this strained cyclic azo compound are also reflected in its UV/Vis spectrum. 1 reacts easily under the influence of acids, heat, or light by an oxidative coupling of both phenyl groups to give 1,10-(2-thiapropano)-5,6-phenan-throline (14). Elimination of sulfur from 1 to give 1,2-diaza[2.2]metacyclophan-1-ene was not successful.
DA  - 1985
DO  - 10.1002/cber.19851181111
LA  - ger
IS  - 11
M2  - 4404
PY  - 1985
SN  - 0009-2940
SP  - 4404-4414
T2  - Chemische Berichte
TI  - 2-Thia-10,11-diaza[3.2]metacyclophan-10-en
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-17835688
Y2  - 2024-12-25T06:30:15
ER  -