TY - THES AB - This study focuses on the thermodynamics and kinetics of the complexation of nickel(II) ions to aspartic acid (Asp), the building block of poly-aspartic acid (PAsp), a biodegradable polyelectrolyte that is extensively used for water and protein purification. Similar to other toxic heavy metal ions, the toxicity of Ni2+ is determined mainly by pH and its speciation. The studies have been performed in aqueous solution, at constant temperature (25°C) and ionic strength (0.1 mol l-1 NaCl), between pH 3 and 8 applying potentiometry, UV-Vis-spectrophotometry and stopped-flow technique. These conditions represent the ionic strength and the pH in natural environments (surface waters, soils, plants). DA - 2004 KW - Nickelion , Komplexbildungsreaktion , Reaktionsmechanismus , Potentiometrie , , LA - eng PY - 2004 TI - pH-sensitive binding of nickel(II) ions to aspartic acid UR - https://nbn-resolving.org/urn:nbn:de:hbz:361-5291 Y2 - 2024-11-22T00:54:27 ER -