TY  - THES
AB  - In this dissertation investigation of one of the existing ring-shaped polyoxomolybdates led to the formation of extended structures and alluded to their potential host functionalities. After realizing such potentials in ring-shaped as well as in spherical giant polyoxomolybdates, and studying the structure of water inside the spherical capsules, this dissertation investigated the stability of some selected spherical polyoxomolybdates in aqueous solution. From this study sites vulnerable to "attack" by degrading agents and hence responsible for their decomposition were proposed and also the role of cations in stabilizing these clusters emerged. The dissertation concludes with a perspective for some open questions regarding the generation of the giant polyoxomolybdates from an ionic soup.
DA  - 2005
KW  - Polyoxomolybdate
KW  - Kristallwachstum
KW  - Wirt-Gast-Beziehung
KW  - Polyoxomolybdates
KW  - Extended structures
KW  - Host-guest chemistry
KW  - Stability studies
LA  - eng
PY  - 2005
TI  - Giant polyoxomolybdates : syntheses, structure and stability studies : from syntheses of extended structures to novel host design, stability investigations in solution and perspectives for a future mechanistic study
UR  - https://nbn-resolving.org/urn:nbn:de:hbz:361-6874
Y2  - 2024-11-22T05:20:38
ER  -