TY  - JOUR
AB  - In this contribution we report on fluorotrimethyl[(Z )‐pentafluoropropen‐1‐yl]phosphorane as a phosphorus based fluorinating reagent. Its solid state structure can be described as a trigonal bipyramid featuring elongated axial bonds due to the formation of a 3‐center 4‐electron bond. Abstraction of the fluoride ion leads to a shortening of the axial P–C bond. Thus the title compound can be utilized for substitution of bromine with fluorine and for the transfer of fluoride ions onto electrophilic compounds. Reaction with Sn(C2F5)2Br2 afforded salt [P(CH3)3(C3F5)]2[Sn(C2F5)2F4]. When fluorotrimethyl[(Z )‐pentafluoropropen‐1‐yl]phosphorane was treated with P(C2F5)2F the primarily produced anion is sufficiently nucleophilic to attack the propenyl group of the cation in β‐position to the phosphorus atom to yield zwitterionic [Me3PCF=C(CF3)–PF3(C2F5)2].
DA  - 2020
DO  - 10.1002/zaac.202000047
KW  - Inorganic Chemistry
LA  - eng
IS  - 13
M2  - 784
PY  - 2020
SN  - 0044-2313
SP  - 784-789
T2  - Zeitschrift für anorganische und allgemeine Chemie
TI  - Fluorotrimethyl[(Z)-pentafluoropropen-1-yl]phosphorane: Structure, Bonding, and Reactivity
UR  - https://nbn-resolving.org/urn:nbn:de:0070-pub-29450881
Y2  - 2024-11-22T05:27:06
ER  -