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Aleksandrov, Krasimir: Preparation, structure and properties of new ternary chalcogenides and germanides of the metals from the first transition series, Cr, Mn, Fe and Ni. 2005
Inhalt
Acknowledgements
Contents
1 Introduction
2 Motivation
3 Experimental
3.1 Preparation procedure
3.2 Vacuum technique
3.3 X – ray characterization methods
3.4 Thermal analysis
3.5 Scanning electron microscopy
3.6 Infrared spectroscopy
3.7 Magnetic measurement
4 The compound Mn2GeSe4
4.1 Introduction
4.2 Preparation and properties
4.3 Characterization
4.4 Single crystal analysis
4.5 Structure description and discussion
4.6 MAPLE calculations
4.7 Olivine or spinel structure
4.8 Magnetic measurements
5 Cr2Ge2Se6 – a new member of M2X2Y6 compounds (M = Transition metal, X = Si, Ge, Y = Chalcogen)
5.1 Structure – chemical relations
5.2 Preparation and properties
5.3 Characterization
5.4 Outlook
6 M3GeTe2 compounds (M = Fe, Ni)
6.1 Introduction
6.2 The compound Fe3GeTe2
6.3 The compound Ni3GeTe2
7 Synthesis and characterization of nanoscale hydroxylapatite
7.1 Introduction
7.2 Experimental outline
7.3 Results and discussion
8 Preliminary experiments to synthesise new ternary transition metal chalcogenides
8.1 Research on transition metal olivines, A2BX4 ds (A = transition metal; B = Si, Ge, Sn; X = Se, Te)
8.2 Attempts to prepare ternary compounds of the type M2X2Y6 (M = transition metal, X = Si, Ge, Sn, Y = S, Se, Te)
8.3 Research on M3BX2 compounds (M = transition metal, B = Si, Ge, Sn, X = Se, Te)
9 Summary
10 References
11 Appendix
11.1 Data for Mn2GeSe4
11.2 Data for Cr2Ge2Se6
11.3 Data for Fe3GeTe2
11.4 Data for Ni3GeTe2