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Choe, Hyeokmin: Dynamics of strain and domains in single crystal and ceramic ferroelectrics under an alternating electric field using stroboscopic time-resolved X-ray [...]. 2018
Inhalt
Abstract
Zusammenfassung
Table of Contents
Chapter 1 Introduction – It is time to explore the exciting new world!
1.1. Motivation
1.2. Stroboscopic time-resolved diffraction methods
1.3. Structural dynamics study of strain and domains in ferroelectrics using stroboscopic time-resolved diffraction techniques
1.4. The present work
1.5. List of publications in association with this work
Chapter 2 Ferroelectric materials
2.1. General remarks on ferroelectrics
2.2. Polarization switching and hysteresis loop in ferroelectrics
2.3. Domain patterns in ferroelectrics
2.4. Electromechanical coupling in ferroelectrics
2.5. Crystallography of ferroelectric perovskites
Chapter 3 X-ray diffraction
3.1. Basic physical principle of X-ray diffraction
3.2. Ewald sphere
3.3. Single crystal X-ray diffraction
3.4. Powder diffraction for polycrystalline samples
Chapter 4 Stroboscopic data-acquisition for time-resolved X-ray diffraction
4.1. Operating principle of stroboscopic data-acquisition system
4.2. New strategies for stroboscopic time-resolved X-ray diffraction
4.3. Conclusion
Chapter 5 Stroboscopic time-resolved high-resolution reciprocal space mapping study of Na0.5Bi0.5TiO3 single crystal under an alternating electric field
5.1. Introduction
5.2. Experiment: stroboscopic time-resolved reciprocal space mapping under an alternating electric field
5.3. Results
5.4. Interpretation and discussion
5.5. Conclusion
Chapter 6 Time-resolved X-ray diffraction study of a uniaxial Sr0.5Ba0.5Nb2O6 ferroelectric single crystal under an alternating electric field
6.1. Introduction
6.2. Experiment: Time-resolved rocking curves under an alternating electric field
6.3. A New mechanism of an enhanced piezoelectricity in uniaxial ferroelectrics under an applied over-coercive field
6.4. Nonlinear response of uniaxial ferroelectrics under sub-coercive fields
6.5. Conclusion
Chapter 7 Time-resolved X-ray powder diffraction study of BaTiO3-based ferroelectric ceramics: Polarization reversal and strain response under an alternating electric field
7.1. Introduction
7.2. Experiments
7.3. Experimental results
7.4. Interpretation and discussion
7.5. Conclusion
Chapter 8 Summary
Appendix A. Installation/Operation of the data-acquisition systems
A.1. Installation/Operation for the first data-acquisition system (FPGA-board, version 2010)
A.2. Installation/Operation for the second data-acquisition system (FPGA-board, version 2016)
A.3. Installation/Operation for the microcontroller-based third data-acquisition system
Appendix B. Drawings of the designed sample holders
B.1. Sample holder I (for single crystals)
B.2. Sample holder II (for polycrystalline samples)
Appendix C. Fitting procedure for two-dimensional reciprocal space maps
C.1. Two-dimensional fitting process
C.2. The fitting results for all parameters
Appendix D. Animations of the time-resolved two-dimensional reciprocal space maps and a model of the monoclinic distortion
Appendix E. Time-resolved rocking curves of Sr0.5Ba0.5NbO6 under an alternating electric field
References
Acknowledgements