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Reiser, Mario: A nanorheology study on the viscoelastic properties of photorheological liquids by x-ray photon correlation spectroscopy. 2020
Inhalt
Contents
Introduction
Theoretical Concepts and Measurement Techniques
Transport Phenomena
The Structure and Dynamics of Wormlike Micelles
Viscoelasticity and the Maxwell Model
Rheometry
Photorheological Liquids
Nanoparticle Dynamics in Complex Liquids and Nanorheology
Obtaining the Complex Modulus from Nanorheology
X-Ray Scattering Techniques
Small Angle X-Ray Scattering
Coherent X-Ray Scattering and Speckles
X/ray Photon Correlation Spectroscopy
Experimental Realization
Sample Preparation
Rheometry Setup
Synchrotron Radiation
Synchrotron Beamline Setups
Development of Measurement Protocols
Data Analysis and Data Processing
Composing Correlation Functions from Low Count Speckle Patterns
Parameter Estimation with Multi-Mode Exponential Models
Discussion
Anomalous Concentration Dependence and Intermicellar Branching Investigated by Rheology
Nanoparticle Dynamics and XPCS Results
Anomalous Dynamics Induced by Confinement and Particle-Network Interaction
The Influence of UV Illumination on the Stress Relaxation and the Long-Range Connectivity of the Network
High-Frequency Strain-Stiffening Due to Nanoscale Rigidity
Conclusion and Outlook
Appendix
Bibliography