We consider simple mean field continuum models for first order liquid–liquid demixing and solid–liquid phase transitions and show how the Maxwell construction at phase coexistence emerges on going from finite-size closed systems to the thermodynamic limit. The theories considered are the Cahn–Hilliard model of phase separation, which is also a model for the liquid-gas transition, and the phase field crystal model of the solid–liquid transition. Our results show that states comprising the Maxwell line depend strongly on the mean density with spatially localized structures playing a key role in the approach to the thermodynamic limit.
Titelaufnahme
Titelaufnahme
- TitelFirst order phase transitions and the thermodynamic limit
- Verfasser
- Erschienen
- AnmerkungFinanziert durch den Open-Access-Publikationsfonds der Westfälischen Wilhelms-Universität Münster (WWU Münster).
- SpracheEnglisch
- Bibl. ReferenzNew Journal of Physics 21 (2019) 123021, 1-21
- DokumenttypAufsatz in einer Zeitschrift
- Schlagwörter (EN)
- URN
- DOI
Zugriffsbeschränkung
- Das Dokument ist frei verfügbar
Links
- Social MediaShare
- Nachweis
- IIIF
Dateien
Klassifikation
Abstract
Statistik
- Das PDF-Dokument wurde 3 mal heruntergeladen.