TY  - JOUR
AB  - Pathway complexity, hierarchical organization, out of equilibrium, and metastable or kinetically trapped species are common terms widely used in recent, high-quality publications in the field of supramolecular polymers. Often, the terminologies used to describe the different self-assembly pathways, the species involved, as well as their relationship and relative stability are not trivial. Different terms and classifications are commonly found in the literature, however, in many cases, without clear definitions or guidelines on how to use them and how to determine them experimentally. The aim of this Minireview is to classify, differentiate, and correlate the existing concepts with the help of recent literature reports to provide the reader with a general insight into thermodynamic and kinetic aspects of complex supramolecular polymerization processes. A good comprehension of these terms and concepts should contribute to the development of new complex, functional materials.
AU  - Matern, Jonas
AU  - Dorca, Yeray
AU  - Sánchez, Luis
AU  - Fernández, Gustavo
DA  - 2019-09-30
DO  - 10.1002/anie.201905724
KW  - Hierarchie
KW  - Nicht-Equilibrium-Systeme
KW  - Pathway-Complexity
KW  - Selbstassemblierung
KW  - Supramolekulare Polymere
KW  - hierarchy
KW  - out-of-equilibrium systems
KW  - pathway complexity
KW  - self-assembly
KW  - supramolecular polymers
LA  - eng
N1  - Angew. Chem. Int. Ed. (2019) 58, 16730-16740
N1  - This work was supported by the MINECO of Spain (CTQ2017-82706-P) and the Comunidad de Madrid (P2018/NMT-4389) and the European Commission (ERC-StG2016-SUPRACOP-715923).
PY  - 2019-09-30
TI  - Revising Complex Supramolecular Polymerization under Kinetic and Thermodynamic Control
TT  - Revision komplexer supramolekularer Polymerisation unter kinetischer und thermodynamischer Kontrolle
UR  - https://nbn-resolving.org/urn:nbn:de:hbz:6-30189392567
Y2  - 2024-11-22T10:12:30
ER  -