TY  - JOUR
AB  - We exploited the inherent geometrical isomerism of a PtII complex as a new tool to control supramolecular assembly processes. UV irradiation and careful selection of solvent, temperature, and concentration leads to tunable coordination isomerism, which in turn allows fully reversible switching between two distinct aggregate species (1D fibers 2D lamellae) with different photoresponsive behavior. Our findings not only broaden the scope of coordination isomerism, but also open up exciting possibilities for the development of novel stimuli-responsive nanomaterials.
AU  - Bäumer, Nils
AU  - Kartha, Kalathil K.
AU  - Allampally, Naveen Kumar
AU  - Yagai, Shiki
AU  - Albuquerque, Rodrigo Q.
AU  - Fernández, Gustavo
DA  - 2019-09-09
DO  - 10.1002/anie.201908002
KW  - Koordinationsisomerie
KW  - Photoresponsives Verhalten
KW  - Selbstassemblierung
KW  - Supramolekulare Polymere
KW  - p-Konjugierte Systeme
KW  - coordination isomerism
KW  - photoresponsive behavior
KW  - self-assembly
KW  - supramolecular polymers
KW  - p-conjugated systems
LA  - eng
N1  - Angew. Chem. Int. Ed. (2019) 58, 15626-15630
N1  - This work was supported by the European Commission (ERC-StG-2016 SUPRACOP-715923).
PY  - 2019-09-09
TI  - Exploiting Coordination Isomerism for Controlled Self-Assembly
TT  - Kontrolle über Selbstassemblierung durch Ausnutzung von Koordinationsisomerie
UR  - https://nbn-resolving.org/urn:nbn:de:hbz:6-30189443346
Y2  - 2024-12-28T01:52:56
ER  -