TY  - JOUR
AB  - Statistical copolymerization plays a key role in many biological and technological processes; however, mechanistic understanding of the formation of analogous supramolecular counterparts remains limited. Herein, we report detailed insights into the supramolecular co-assembly of two p-conjugated PdII and PtII complexes, which in isolation self-assemble into flexible fibers and nanodisks, respectively. An efficient single-step co-assembly into only one type of nanostructure (fibers or nanodisks) takes place if any of the components is in excess. In contrast, equimolar mixtures lead to PdII-rich fiber-like co-assemblies by a statistical co-nucleation event along with a residual amount of self-sorted nanodisks in a stepwise manner.
AU  - Coelho, Joao Paulo
AU  - Matern, Jonas
AU  - Albuquerque, Rodrigo Q.
AU  - Fernández, Gustavo
DA  - 2019-04-26
DO  - 10.1002/chem.201900604
KW  - PtII-Komplexe
KW  - Selbstorganisation
KW  - Selbstsortierung
KW  - supramolekulare Polymere
KW  - p-konjugierte Systeme
KW  - PtII complexes
KW  - self-assembly
KW  - self-sorting
KW  - supramolecular polymers
KW  - p-conjugated systems
LA  - eng
N1  - Chem. Eur. J. (2019) 25, 8960-8964
N1  - This work was supported by the the Humboldt Foundation (Sofja-Kovalevskaja Award) and the European Commission (ERC-StG-2016 SUPRACOP-715923).
PY  - 2019-04-26
TI  - Mechanistic Insights into Statistical Co-Assembly of Metal Complexes
TT  - Mechanistische Einblicke in die statistische Co-Assemblierung von Metallkomplexen
UR  - https://nbn-resolving.org/urn:nbn:de:hbz:6-30189431511
Y2  - 2024-11-24T09:25:48
ER  -