The first 3-methanediyl-1,3,5,6-tetraphosphabicyclo[3.1.0]hex-2-ene. Evidence for a [3 + 2] cycloaddition of a 2,4,5,6-tetraphosphahepta-1,3,6-triene

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Titel
The first 3-methanediyl-1,3,5,6-tetraphosphabicyclo[3.1.0]hex-2-ene. Evidence for a [3 + 2] cycloaddition of a 2,4,5,6-tetraphosphahepta-1,3,6-triene
Verfasser
Weber, Lothar ; Kirchhoff, Ralf ; Stammler, Hans-Georg ; Neumann, Beate
Enthalten in
Journal of the Chemical Society, Chemical Communications, Jg. 1992 H. 11, S. 819-820
Erschienen
1992
Sprache
Englisch
Dokumenttyp
Aufsatz in einer Zeitschrift
ISSN
0022-4936
URN
urn:nbn:de:0070-pub-17748306
DOI
10.1039/C39920000819

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Abstract

Reaction of ([eta]5C5Me5)(CO)2 FeP(SiMe3)2 with three equivalents of Cl–P[doublebond]C(SiMe3)2 affords the first 3-methanediyl-1,3,5,6-tetraphosphabicyclo[3.1.0.]hex-2-ene 7, the molecular structure of which has been determined by X-ray analysis.

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