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  • Titel
    Supramolekulare Selbstassemblierungs- und Erkennungsphänomene von Resorcin[4]arenen
  • Verfasser
    Schnatwinkel, Björn
  • Gutachter
    Mattay, Jochen
  • Erschienen
    2008
  • Sprache
    Deutsch
  • Dokumenttyp
    Dissertation
  • Schlagwörter
    , ,
  • URN
    urn:nbn:de:hbz:361-14038 
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Abstract
  • The design of selective and effective binding host-guest systems are an important challenge in modern supramolecular chemistry. Calixarenes are potent size-selective receptors for a variety of substrates, in particular, for inorganic and organic cations. During the last two decades, resorcin[4]arenes - members of the calixarene family - have attracted broad interest in supramolecular chemistry and molecular recognition.
    In the course of this dissertation a systematical investigation of the complexation behaviour of several quaternary ammonia ions regarding resorcin[4]arene, its methylated derivative and pyrogallo[4]arenes was accomplished by using microcalorimetry techniques in order to elucidate the thermodynamical aspects.
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